This is based on the fact that it is difficult for a dislocation to pass into another grain, especially if it is very misaligned. Atomic disorder at the boundary causes discontinuity in slip planes. For high-angle grain boundaries, stress at end of slip plane may trigger new dislocations in adjacent grains. Small angle grain boundaries are not effective in blocking dislocations.
The finer the grains, the larger the area of grain boundaries that impedes dislocation motion. Grain-size reduction usually improves toughness as well. Grain size can be controlled by the rate of solidification and by plastic deformation.
